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Total [RO 2 ] was estimated to be maximum 1. More Product Information Below. To compensate the strong loss via photolysis, a comparably strong unknown source is necessary as the heterogeneous NO 2 conversion or the gas-phase reaction of OH and NO is insignificant.

03818 legrand pdf

This correction of chemical interferences ascertained excellent agreement with the absolute differential optical absorption spectroscopy DOAS measurements, both in a smog chamber and under urban 0818 conditions Kleffmann et al. This temperature dependence exists not only for equilibrium over soil solution but also levrand adsorption—desorption equilibrium over dry and humid soil surfaces Li legranc al.

The field site is characterized by light vegetation cover, mainly comprising small shrubs like Pistacia lentiscus, Sarcopoterium spinosum and Nerium oleander ; herbs like Inula viscosa and Foeniculum vulgare ; and few typical Mediterranean trees like Olea europaea, Pinus sp.

No rain was observed, but the elevated field site was impacted lfgrand fog during nighttime and early morning due to adiabatic cooling of ascending marine humid air masses.

On Cyprus, diel profiles of HONO showed peak values in the late morning and persistently high mixing ratios during daytime, as has been reported for some other remote regions Acker et al. Recently an enhancement of the photolysis frequency of particulate nitrate relative to gaseous or aqueous nitrate was found Ye et al. This similarity and their dependency on relative humidity are suggestive of a common source for both reactive nitrogen species. The measuring site was located on a military compound in Ineia, Cyprus Nalpak Video Sales, Inc.


Analyzing microbial surface communities from drylands, Weber et al.

In contrast, in a humid regime HONO mixing legrans were continuously high during nighttime and showed less pronounced morning peaks, suggesting lower nighttime deposition of NO 2 and lower HONO emissions in the morning, respectively. Contact Key Code Media, Inc. The yellow and blue boxes reflect the dry and the humid periods, respectively. Due to low local anthropogenic impact and low NO x levels in aged air masses, but high solar radiation, this is an ideal site at which to investigate possible HONO sources and to gain a better understanding of HONO chemistry.

However, high values were observed at remote lergand sites, with mean values of 0. Within the main local wind direction of SW Fig. HONO was measured with a commercial long-path legrnd photometry instrument effective light path 1. The reagents were all high-purity-grade chemicals, i. In the first stripping coil HONO is quantitatively collected.


Similar profiles were also observed for other trace gases, like isoprene or DMS, which are transported in upslope winds. Likewise, HONO formation lehrand in surface-bound water are about 4 038188 of magnitude larger than expected for the aqueous-phase reaction Pitts et al.

Besides two different air mass origins, two periods with different behavior of relative humidity were identified, as illustrated by blue and yellow boxes in Fig. Based on a formula for photo-enhanced conversion of NO 2 on humic acid aerosols which was derived by Stemmler et al. It plays a key role in the oxidizing capacity of the atmosphere, as it is an important precursor of the OH radical, which initiates most atmospheric oxidations.


This forms the 038818 daytime HONO source responsible for morning concentration peaks and consistently high daytime mixing ratios at the Cyprus field site. Thinklogical, A Belden Brand. Snaps into patch panels and compatible wall plates and surface boxes. Due to low and invariant acetonitrile levels, anthropogenic activity and local biomass burning can be excluded as an NO source at this specific site. The stripping coils are temperature-controlled by a water-based thermostat, and the whole external sampling unit is shielded from sunlight by a small plastic housing.

However, kinetic models of competitive adsorption of 03188 gases and water onto particle surfaces predict exchange behavior explicitly distinct from the legran phase Donaldson et al.

The four red points mark the main cities of Cyprus: The budget analysis for NO for both humidity regimes is illustrated in Fig.

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They spent more time over continental terrestrial surface and were likely to be additionally affected by biomass burning events detected in eastern Europe within the measurement periods FIRMS, MODIS, web fire mapper, Fig.

For both periods the contributions are quiet similar; just the absolute values are different. Here the approach for the nighttime conversion frequency by, e.

Accordingly, the respective air mass travel time over land is estimated to be about half an hour, which is somewhat longer than the daytime lifetime of HONO and might provide enough time for the equilibrium processes. Littlite – CAE, Inc.